Porosity and Geomechanical Characteristics of banded Iron Ore from Itakpe, North Central Nigeria
Authors
- Amidu Abiola Ige-Adeyeye
- Olawale Babatunde Olatinsu
- Vitalis Chidi Ozebo
- Lionel Esteban
Keywords:
Itakpe iron ore, porosity, uniaxial compressive strength, elastic modulus, modulus ratioAbstract
The microstructural characteristics of geological materials are fundamentally influenced by their pore configuration and geomechanical properties. The banded iron ore samples from Itakpe, North Central Nigeria, have been examined using: (i) X-ray fluorescence (XRF) spectroscopy for preliminary iron content assessment; (ii) low-field nuclear magnetic resonance (NMR) and water imbibition porosity (WIP) techniques for pore structure evaluation; and (iii) bulk density and stress-strain analysis for the geomechanical characterisation. The average weight of haematite, silica, alumina and iron contents in the samples are 53%, 22%, 12%, and 37%, respectively. These values show that the Itakpe iron ores are low-grade and hence, significant enrichment is required for economic viability. The pore system of the ore samples is basically bimodal without any indication of macropores, in agreement with the metasedimentary origin of the ores. The transverse relaxation time ranges for the pore regions are: (a) micropores (0.2818 – 1.413 ms) and (b) mesopores (7.943 – 79.43 ms). The mean porosities estimated via NMR and WIP techniques are 0.365 p.u. and 0.488 p.u., respectively. Computed porosity and water content from NMR and WIP techniques show high degree of correlation which are 87% and 76%, respectively. The average UCS, elastic modulus and dry bulk density of the samples are 101.28 MPa, 3.94 GPa and 3.46 g/cm3, respectively showing high strength ores. The plots of UCS versus dry bulk density for the samples shows an increasing exponential relation, while the UCS versus NMR porosity, modulus ratio versus dry bulk density as well as modulus ratio versus UCS all show decreasing exponential relations. The UCS is negatively correlated with NMR porosity but positively correlated with bulk density. Integrating NMR and geomechanical techniques can reliably: (i) predict mechanical behaviour without destructive testing; (ii) complement traditional porosity methods; and (iii) assist in mine design for safety and ore optimisation.
Author Biographies
Amidu Abiola Ige-Adeyeye
Department of Physical Science, Lecturer II
Olawale Babatunde Olatinsu
Department of Physics, Senior Lecturer
Vitalis Chidi Ozebo
Department of Physics, Professor
Lionel Esteban
NMR Lab, CSIRO, Senior Research Fellow
Adebimpe, R.A., 2013. Mine Equipment Selection for Ajabanoko Iron Ore Deposit, Kogi State, Nigeria. Science Research, 1, 25. https://doi.org/10.11648/j.sr.20130102.13.
Adedeji, F.A. and Sale, F.R., 1984. Characterization and reducibility of Itakpe and Agbaja (Nigerian) iron ores. Clay miner. 19, 843 – 856. https://doi.org/10.1180/claymin.1984.019.5.12
Adejuwon, B., Ibeneme Sabinus, I., Osizemete, A., Obioha Young, E., Abba, A., 2020. Quality Assessment and Reserve Estimation of the Egnaeja Iron Ore Deposit, North Central Nigeria using Integrated Approach. International Journal of Earth Science and Geophysics, 6, 2. https://doi.org/10.35840/2631-5033/1837.
Afeni, T.B., Lawal, A.I., Adeyemi, R.A., 2020. Re-examination of Itakpe iron ore deposit for reserve estimation using geostatistics and artificial neural network techniques. Arab J Geosci 13, 657. https://doi.org/10.1007/s12517-020-05644-9.
Akande, S., Ajaka, E.O., Alabi, O.O., Olatunji, T.A., 2020. Effects of varied process parameters on froth flotation efficiency: A case study of Itakpe iron ore. Nig. J. Tech. 39, 807 – 815. https://doi.org/10.4314/njt.v39i3.21.
Akinrinsola, A.O., Adekeye, J.I.D., 1993. A geostatistical ore reserve estimation of the Itakpe iron ore deposits, Okene, Kogi State. Journ. Mining. And Geology 29, 19–25.
Alabi, O. O., Sedara, S. O., Olatona, G. I., Olaleye, A. O., & Kasali, A. A. (2025). Mineral Resource Exploration Potential in the Ado-Ekiti-Ilesa Region of Southwest, Nigeria using Aeromagnetic Survey. Nigerian Journal of Physics, 34(3), 43-52.
Ameh, E.G., 2014. Geochemical distribution of heavy metals in soil around Itakpe iron-ore mining area-a statistical approach. Research journal of environmental and earth sciences 6, 118–126.
Amigun, J.O., Ako, B.D., 2009. Rock density-A tool for mineral prospection: A case study of Ajabanoko iron ore deposit, Okene SW Nigeria. The pacific journal of science and technology 10, 733–741.
Annor, A.E., Freeth, S.J., 1985. Thermo-tectonic evolution of the basement complex around Okene, Nigeria, with special reference to deformation mechanism. Precambrian Research 28, 269–281.
Anovitz, L.M., Cole, D.R., 2015. Characterization and Analysis of Porosity and Pore Structures. Reviews in Mineralogy and Geochemistry 80, 61–164. https://doi.org/10.2138/rmg.2015.80.04.
Anudu, G.K., Stephenson, R.A., Macdonald, D.I.M., 2014. Using high-resolution aeromagnetic data to recognise and map intra-sedimentary volcanic rocks and geological structures across the Cretaceous middle Benue Trough, Nigeria. Journal of African Earth Sciences 99, 625–636. https://doi.org/10.1016/j.jafrearsci.2014.02.017.
Armstrong, P., Knieke, C., Mackovic, M., Frank, G., Hartmaier, A., Göken, M., Peukert, W., 2009. Microstructural evolution during deformation of tin dioxide nanoparticles in a comminution process. Acta Materialia 57, 3060 – 3071. https://doi.org/10.1016/j.actamat.2009.02.049.
Atapour, H., Mortazavi, A., 2018a. The effect of grain size and cement content on index properties of weakly solidified artificial sandstones. J. Geophys. Eng. 15, 613 – 619. https://doi.org/10.1088/1742-2140/aaa14a
Atapour, H., Mortazavi, A., 2018b. The influence of mean grain size on unconfined compressive strength of weakly consolidated reservoir sandstones. Journal of Petroleum Science and Engineering 171, 63–70. https://doi.org/10.1016/j.petrol.2018.07.029
Attewell, P.B. and Farmer, I.W. (1976) Principles of Engineering Geology. Chapman and Hall, London. https://doi.org/10.1007/978-94-009-5707-7.
Bell, F.G. and Lindsay, P. 1999. The petrographic and geomechanical properties of some sandstones from the Newspaper Member of the Natal Group near Durban, South Africa. Eng. Geol. 53, 57-81.
Bello, R., Onifade, Y.S., 2016. Discrimination of reservoir fluid contacts using compressional and shear wave velocity. Glo Jnl Pure Appl Sci 22, 177. https://doi.org/10.4314/gjpas.v22i2.7
Benavides, F., Leiderman, R., Souza, A., Carneiro, G., Bagueira De Vasconcellos Azeredo, R., 2020. Pore size distribution from NMR and image-based methods: A comparative study. Journal of Petroleum Science and Engineering 184, 106321. https://doi.org/10.1016/j.petrol.2019.106321
Bett, A. K. and Maranga, S. M. (2012). Considerations for Beneficiation of Low-Grade Iron Ore for Steel Making in Kenya. Proceedings of the 2012 Mechanical Engineering Conference on Sustainable Research and Innovation, Volume 4, 3rd-4th May 2012.
Beukes, N. J., Gutzmer, J., & Mukhopadhyay, J. (2003). The geology and genesis of high-grade hematite iron ore deposits. Applied Earth Science, 112(1), 18–25. https://doi.org/10.1179/037174503225011243.
Bevilacqua, P., Ferrara, G., 1996. Comminution of porous materials. International Journal of Mineral Processing 44–45, 117–131. https://doi.org/10.1016/0301-7516(95)00023-2
Blümich, B., 2019. Low-field and benchtop NMR. Journal of Magnetic Resonance 306, 27–35. https://doi.org/10.1016/j.jmr.2019.07.030
Blümich, B., Casanova, F., Appelt, S., 2009. NMR at low magnetic fields. Chemical Physics Letters 477, 231–240. https://doi.org/10.1016/j.cplett.2009.06.096
Bradshaw, D., 2014. The role of process mineralogy in improving the process performance of complex sulphide ores, in: Proceedings of the XXVII International Mineral Processing Congress. pp. 1–23.
Carr, H.Y., Purcell, E.M., 1954. Effects of diffusion on free precession in nuclear magnetic resonance experiments. Phys. Rev. 94, 630–638. https://doi.org/10.1103/PhysRev.94.630
Casieri, C., De Luca, F., Nodari, L., Russo, U., Terenzi, C., 2010. Detection of magnetic environments in porous media by low-field 2D NMR relaxometry. Chemical Physics Letters 496, 223–226.
Chatterjee, R. and Mukhopadhyay, M. 2002. Petrophysical and geomechanical properties of rocks from the oilfields of the Krishna-Godavari and Cauvery Basins, India. Bull. Eng. Geol. Environ. 2002, 61, 169–178.
Chindaprasirt, P., Hatanaka, S., Mishima, N., Yuasa, Y. and Chareerat, T., 2009. Effects of binder strength and aggregate size on the compressive strength and void ratio of porous concrete. International journal of minerals, metallurgy and materials, 16(6), pp.714-719.
Clout, J.M.F. and Manuel, J.R. (2015). Mineralogical, chemical, and physical characteristics of iron ore. Editor(s): Liming Lu, Iron Ore, Woodhead Publishing, 45-84. https://doi.org/10.1016/B978-1-78242-156-6.00002-2.
Coates, G.R., Xiao, L., Prammer, M.G., 1999. NMR logging: Principles and Interpretation. Halliburton Energy Service, Huston, Texas.
Connolly, P.R.J., Yan, W., Zhang, D., Mahmoud, M., Verrall, M., Lebedev, M., Iglauer, S., Metaxas, P.J., May, E.F., Johns, M.L., 2019. Simulation and experimental measurements of internal magnetic field gradients and NMR transverse relaxation times (T2) in sandstone rocks. Journal of Petroleum Science and Engineering 175, 985–997. https://doi.org/10.1016/j.petrol.2019.01.036
Cores, A., Babich, A., Muñiz, M., Isidro, A., Ferreira, S. and Martin, R. 2007. Iron ores, fluxes and tuyere injected coals used in the blast furnace. Ironmaking and Steelmaking, 34(3), 231-240.
Dalirnasab, A., Marji, M.F., Nejati, H.-R., Mohebi, M., 2024. Effects of porosity on the strength and mechanical behaviour of porous geo-materials under cyclic loading. Rudarsko-geološko-naftni zbornik 39, 15–30. https://doi.org/10.17794/rgn.2024.2.2
Downey, K., Bermel, W., Soong, R., Lysak, D.H., Ronda, K., Steiner, K., Costa, P.M., Wolff, W.W., Decker, V., Busse, F., Goerling, B., Haber, A., Simpson, M.J., Simpson, A.J., 2024. Low‐field, not low quality: 1D simplification, selective detection, and heteronuclear 2D experiments for improving low‐field NMR spectroscopy of environmental and biological samples. Magnetic Reson in Chemistry 62, 345–360. https://doi.org/10.1002/mrc.5401
Dunn, K.-J., Bergman, D.J., LaTorraca, G.A., 2002. Nuclear magnetic resonance: Petrophysical and logging applications. Elsevier.
Fadare, V.O., 1983. Iron Ore Formation—The Okene-Ajaokuta-Lokoja Areas of Kogi State. A Potential Supply Base for Steel Plant at Ajaokuta. Journal of Mining and Geology 20, 209–214.
Faruwa, A.R., Qian, W., Akinsunmade, A., Akingboye, A.S., Dusabemariya, C., 2021. Aeromagnetic and remote sensing characterization of structural elements influencing iron ore deposits and other mineralization in Kabba, southwestern Nigeria. Advances in Space Research 68, 3302–3313. https://doi.org/10.1016/j.asr.2021.06.024
Feng, S., Xu, Z., Chai, J., Li, Y., 2020. Using pore size distribution and porosity to estimate particle size distribution by nuclear magnetic resonance. Soils and Foundations 60, 1011–1019. https://doi.org/10.1016/j.sandf.2020.05.006
Gareev, K.G. (2023). Diversity of Iron Oxides: Mechanisms of Formation, Physical Properties and Applications. Magnetochemistry 2023, 9(5), 119; https://doi.org/10.3390/magnetochemistry9050119.
Gholami, R., Fakhari, N., 2017. Support Vector Machine: Principles, Parameters, and Applications, in: Handbook of Neural Computation. Elsevier, pp. 515–535. https://doi.org/10.1016/B978-0-12-811318-9.00027-2
Golsanami, N., Zhang, X., Yan, W., Yu, L., Dong, H., Dong, X., Cui, L., Jayasuriya, M.N., Fernando, S.G., Barzgar, E., 2021. NMR-Based Study of the Pore Types’ Contribution to the Elastic Response of the Reservoir Rock. Energies 14, 1513. https://doi.org/10.3390/en14051513
Grunewald, E., Knight, R., 2011. A laboratory study of NMR relaxation times in unconsolidated heterogeneous sediments. Geophysics 76, G73–G83. https://doi.org/10.1190/1.3581094.
Han, D. Zhu, J. And Leung, Y. 2022. Failure strength and fracture characteristics of rock with discontinuity under indirect tension. Journal of Rock Mechanics and Geotechnical Engineering, 14(6), 1810-1822. https://doi.org/10.1016/j.jrmge.2022.02.007.
Holmes, R.J. 2013. Overview of the Australian iron ore industry. In: Rankin, W.J. (Ed.), Australian Mining and Metallurgical Operating Practices. The Australian Institute ofMining and Metallurgy: Melbourne, Australia, 1379-1384.
Holmes, R.J. and Lu, L. (2015). Introduction: Overview of the global iron ore industry. Iron Ore, 42p. http://dx.doi.org/10.1016/B978-1-78242-156-6.00001-0. Elsevier Ltd.
Holmes, R.J., Lu, Y. and Lu, L. (2022). Chapter 1 - Introduction: Overview of the global iron ore industry, Editor(s): Liming Lu, In Woodhead Publishing Series in Metals and Surface Engineering, Iron Ore (Second Edition), Woodhead Publishing, 1-56. https://doi.org/10.1016/B978-0-12-820226-5.00023-9.
Ifediegwu, S.I., Nnebedum, D.O., Nwatarali, A.N., 2019. Identification of groundwater potential zones in the hard and soft rock terrains of Kogi State, North Central Nigeria: an integrated GIS and remote sensing techniques. SN Appl. Sci. 1, 1151. https://doi.org/10.1007/s42452-019-1181-1
Ige-Adeyeye, A.A., Olatinsu, O.B., Ozebo, V.C., Esteban, L., 2026. Pore size characterization of Cretaceous ironstone by low-field nuclear magnetic resonance technique. Geosystems and Geoenvironment 5, 100449. https://doi.org/10.1016/j.geogeo.2025.100449
Isah, S. and Aliyu, B. (2024). Unveiling the Mineral Wealth of Kogi State, Nigeria: A Comprehensive Inventory and Assessment. Earth Sciences, 13(6), 246-281. https://doi.org/10.11648/j.earth.20241306.12.
ISRM (2007) The complete ISRM Suggested Methods for rock characterization, testing and monitoring: 1974–2006. In: Ulusay R, Hudson JA (eds) Suggested Methods prepared by the Commission on Testing Methods, International Society for Rock Mechanics, compilation arranged by the ISRM Turkish National Group, Kozan Ofset, Ankara, Turkey.
Iwasaki, I., Prasad, M.S., 1989. Processing Techniques for Difficult-to-treat Ores by Combining Chemical Metallurgy and Mineral Processing. Mineral Processing and Extractive Metallurgy Review 4, 241–276. https://doi.org/10.1080/08827508908952639
Jégourel, Y., 2020. The global iron ore market: From cyclical developments to potential structural changes. The Extractive Industries and Society 7, 1128–1134. https://doi.org/10.1016/j.exis.2020.05.015
Jeng, F.S., Weng, M.C., Lin, M.L., Huang, T.H., 2004. Influence of petrographic parameters on geotechnical properties of tertiary sandstones from Taiwan. Engineering Geology 73, 71–91. https://doi.org/10.1016/j.enggeo.2003.12.001
Jin, S., Zhou, J., Zhao, X., Sun, L., 2021. Quantitative relationship between pore size distribution and compressive strength of cementitious materials. Construction and Building Materials 273, 121727. https://doi.org/10.1016/j.conbuildmat.2020.121727
Ju, Y., Jin, A., Zhao, Y., Tang, S., 2024. Iron ore grade’s impact on uniaxial compression behavior and acoustic emission characteristics. Materials Today Communications 39, 108856. https://doi.org/10.1016/j.mtcomm.2024.108856.
Keating, K., Knight, R., 2007. A laboratory study to determine the effect of iron oxides on proton NMR measurements. Geophysics 72, E27–E32. https://doi.org/10.1190/1.2399445
Keating, K., Knight, R., 2010. A laboratory study of the effect of Fe(II)-bearing minerals on nuclear magnetic resonance (NMR) relaxation measurements. Geophysics 75, F71–F82. https://doi.org/10.1190/1.3386573
Keating, K., Knight, R., 2012. The effect of spatial variation in surface relaxivity on nuclear magnetic resonance relaxation rates. Geophysics 77, E365–E377. https://doi.org/10.1190/geo2011-0462.1
Kenyon, W.E., 1997. Petrophysical Principles of Applications of NMR Logging. The Log Analyst 38.
Khanlari, G.-R., Heidari, M., Sepahigero, A.-A., Fereidooni, D., 2014. Quantification of strength anisotropy of metamorphic rocks of the Hamedan province, Iran, as determined from cylindrical punch, point load and Brazilian tests. Engineering Geology 169, 80–90. https://doi.org/10.1016/j.enggeo.2013.11.014
Kholodov, V.N. and Butuzova, G.Y. (2008). Siderite formation and evolution of sedimentary iron ore deposition in the Earth’s history. Geol. Ore Deposits 50, 299–319 (2008). https://doi.org/10.1134/S107570150804003X.
King, R.P., 1994. Comminution and liberation of minerals. Minerals Engineering 7, 129–140. https://doi.org/10.1016/0892-6875(94)90059-0
Klein, B., Wang, C., Nadolski, S., 2018. Energy-efficient comminution: best practices and future research needs, in: Awuah-Offei, K. (Ed.), Energy Efficiency in the Minerals Industry, Green Energy and Technology. Springer International Publishing, Cham, pp. 197–211. https://doi.org/10.1007/978-3-319-54199-0_11
Kleinberg, R.L., 1996. Utility of NMR T2 distributions, connection with capillary pressure, clay effect, and determination of the surface relaxivity parameter ρ2. Magnetic resonance imaging 14, 761–767.
Kleinberg, R.L., 2001. NMR measurement of petrophysical properties. Concepts in Magnetic Resonance 13, 404–406.
Kleinberg, R.L., Farooqui, S.A., Horsfield, M.A., 1993. T1/T2 ratio and frequency dependence of NMR relaxation in porous sedimentary rocks. Journal of Colloid and Interface Science 158, 195–198.
Kleinberg, R.L., Horsfield, M.A., 1990. Transverse relaxation processes in porous sedimentary rock. Journal of Magnetic Resonance (1969) 88, 9–19. https://doi.org/10.1016/0022-2364(90)90104-H
Korbel, C., Foucaud, Y., Vanderbruggen, A., 2026. Mineral processing applied to the treatment of primary and secondary ores, in: Sustainable Processes in the Circular Economy. Elsevier, pp. 83–122. https://doi.org/10.1016/B978-0-443-28886-9.00007-1
Küblböck, K., Tröster, B., Eigner, M., 2022. Hard facts and environmental impacts: An overview of the global iron and steel sector, ÖFSE Briefing Paper, No. 33. Austrian Foundation for Development Research, Vienna.
Kuila, U., McCarty, D.K., Derkowski, A., Fischer, T.B., Prasad, M., 2014. Total porosity measurement in gas shales by the water immersion porosimetry (WIP) method. Fuel 117, 1115–1129. https://doi.org/10.1016/j.fuel.2013.09.073
Kuila, U., Prasad, M., 2013. Specific surface area and pore‐size distribution in clays and shales. Geophysical Prospecting 61, 341–362. https://doi.org/10.1111/1365-2478.12028
Kumar, M., Jena, S. and Patel, S.K. 2008. Characterization of properties and reduction behaviour of iron ores for application in sponge ironmaking. Mineral Processing and Extractive Metallurgy Review, 29(2), 118-129.
Li, A., Ding, W., Wang, R., He, J., Wang, X., Sun, Y., Gu, Y., Jiao, N., 2017. Petrophysical characterization of shale reservoir based on nuclear magnetic resonance (NMR) experiment: A case study of Lower Cambrian Qiongzhusi Formation in eastern Yunnan Province, South China. Journal of Natural Gas Science and Engineering 37, 29–38. https://doi.org/10.1016/j.jngse.2016.11.034
Li, F., Wang, R., Mao, L., Zhu, D., She, X., Guo, J., Lin, S., Yang, Y., 2022. Evaluation of solar radiation models on vertical surface for building photovoltaic applications in Beijing. IET Renewable Power Gen 16, 1792–1807. https://doi.org/10.1049/rpg2.12478
Li, Huamin, Li, Huigui, Wang, K., Liu, C., 2018. Effect of rock composition microstructure and pore characteristics on its rock mechanics properties. International Journal of Mining Science and Technology 28, 303–308. https://doi.org/10.1016/j.ijmst.2017.12.008
Li, J., Lu, S., Chen, G., Wang, M., Tian, S., Guo, Z., 2019. A new method for measuring shale porosity with low-field nuclear magnetic resonance considering non-fluid signals. Marine and Petroleum Geology 102, 535–543. https://doi.org/10.1016/j.marpetgeo.2019.01.013
Li, M., Wang, D., Shao, Z., 2020. Experimental study on changes of pore structure and mechanical properties of sandstone after high-temperature treatment using nuclear magnetic resonance. Engineering Geology 275, 105739. https://doi.org/10.1016/j.enggeo.2020.105739
Liu, L., Ge, Z., Zhou, Z., Li, Z., Deng, Q., 2024. Mineral composition, pore structure and mechanical properties of coal measure strata rocks: A case study of Pingdingshan Coalfield. Science of The Total Environment 952, 175944. https://doi.org/10.1016/j.scitotenv.2024.175944
Ma, B., Hu, Q., Yang, S., Yin, N., Qiao, H., Zhang, T., Meng, M., 2020. Multiple approaches to quantifying the Effective porosity of lacustrine shale oil reservoirs in Bohai Bay Basin, East China. Geofluids 2020, 1–13. https://doi.org/10.1155/2020/8856620
Ma, S., Jin, G., Sy, R., Kesserwan, H., 2018. Rock grain size prediction from NMR Measurement and digital rock modeling- experimental validation, in: All Days. Presented at the SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, SPE, Dammam, Saudi Arabia, p. SPE-192220-MS. https://doi.org/10.2118/192220-MS
Madureira, N.L. (2012). The iron industry energy transition. Energy Policy, 50, 24-34. https://doi.org/10.1016/j.enpol.2012.03.003.
McNulty, T., Hazen, N., Park, S., 2022. Processing the ores of rare-earth elements. MRS Bulletin 47, 258–266. https://doi.org/10.1557/s43577-022-00288-4
Meiboom, S., Gill, D., 1958. Modified spin-echo method for measuring nuclear relaxation times. Review of scientific instruments 29, 688–691.
Mitchell, J., 2010. Nuclear magnetic resonance relaxation and diffusion in the presence of internal gradients: The effect of magnetic field strength. Phys. Rev. E 81. https://doi.org/10.1103/PhysRevE.81.026101
Mondal, I., Singh, K.H., 2023. Fluid substitution in NMR T2 distribution and resistivity independent saturation computation using synthetic capillary pressure data. Petroleum Research 8, 77–86. https://doi.org/10.1016/j.ptlrs.2022.03.004
Muwanguzi, A.J.B., Karasev, A.V., Byaruhanga, J.K. and Jönsson, P.G. (2012a). Characterisation of the Physical and Metallurgical Properties of Natural Iron Ore for Iron Production. International Scholarly Research Network (ISRN) Materials Science Volume, Article ID 147420, 9 p. https://doi.org/10.5402/2012/147420.
Muwanguzi, A.J.B., Karasev, A.V., Byaruhanga, J.K. and Jönsson, P.G. (2012b). Characterization of Chemical Composition and Microstructure of Natural Iron Ore from Muko Deposits. International Scholarly Research Network (ISRN) Materials Science Volume, Article ID 174803, 9 p. https://doi.org/10.5402/2012/174803.
Nilsen, B., Palmström, A., 2000. Engineering geology and rock engineering, handbook no. 2. Norwegian Soil and Rock Engineering Association, Oslo, Norway.
Niu, Q., Zhang, C., 2018. Joint inversion of NMR and SIP data to estimate pore size distribution of geomaterials. Geophysical Journal International 212, 1791–1805. https://doi.org/10.1093/gji/ggx501
O’Connor, J. M., Manuel, J. R., and Clout, J. M. F. (2000). Relationships between index test results and uniaxial compressive strength. Proceedings of the 4th International Conference on Geotechnical Engineering (GEOTECH-YEAR 2000), Bangkok, Thailand, 27–30 November 2000.
Obaje, N.G., 2009. Geology and Mineral Resources of Nigeria, Lecture Notes in Earth Sciences. Springer Berlin Heidelberg, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-92685-6.
Odigi, M.I., 2002. Geochemistry and geotectonic setting of migmatitic gneisses and amphibolites in the Okene-Lokoja area of southwestern Nigeria. Journal of mining and geology 38, 81–90.
Olade, M.A., 1978. Early Cretaceous basalt volcanism and initial continental rifting in Benue Trough, Nigeria. Nature 273, 458–459. https://doi.org/10.1038/273458a0
Olade, M.A., 1980. Precambrian metallogeny in West Africa. Geol Rundsch 69, 411–428. https://doi.org/10.1007/BF02104546
Olade, M.A., 2019. Geological Re-Evaluation of Nigeria’s Iron Ore Deposits as Raw Materials for a Viable Iron and Steel Industry. Achievers J. Sci. Research 2, 1–22.
Olatinsu, O.B., Olorode, D.O., Clennell, B., Esteban, L., Josh, M., 2017. Lithotype characterizations by Nuclear Magnetic Resonance (NMR): A case study on limestone and associated rocks from the eastern Dahomey Basin, Nigeria. Journal of African Earth Sciences 129, 701–712. https://doi.org/10.1016/j.jafrearsci.2017.02.005.
Oyedele, K., Oladele, S. and Salami, A., 2016. Geophysical investigation of banded iron ore mineralization at Ero, North–Central Nigeria. Materials and Geoenvironment, 63(2), 109-118. https://doi.org/10.1515/rmzmag-2016-0010.
Palchik, V., 2011. On the ratios between elastic modulus and uniaxial compressive strength of heterogeneous carbonate rocks. Rock Mech Rock Eng 44, 121–128. https://doi.org/10.1007/s00603-010-0112-7
Pamparana, G., Klein, B., Bergerman, M.G., 2024. Impact of the feed particle size distribution and its packing characteristics on compression comminution. Minerals Engineering 218, 108934. https://doi.org/10.1016/j.mineng.2024.108934
Peng, J., Wong, L.N.Y., Liu, G. and Teh, C.I. 2019. Influence of initial micro-crack damage on strength and micro-cracking behavior of an intrusive crystalline rock. Bull Eng Geol Environ 78, 2957–2971. https://doi.org/10.1007/s10064-018-1317-3.
Pereira, L., Schach, E., Tolosana-Delgado, R., Frenzel, M., 2023. All About Particles: Modelling Ore Behaviour in Mineral Processing. Elements 19, 359–364. https://doi.org/10.2138/gselements.19.6.359
Pereira, M.L., Pappalardo, L., Buono, G., Cueto, N., Vázquez-Calvo, C., Fort, R., Costa E Silva, M., Fernandes, I., Zanon, V., Amaral, P., 2025. A multi-method approach in the physical and mechanical assessment of lava rocks with distinct microstructure. Engineering Geology 346, 107907. https://doi.org/10.1016/j.enggeo.2025.107907
Rahaman, M.A., Ocan, O., 1978. On relationships in the Precambrian migmatic gneisses of Nigeria. Nigeria J. Min. Geol. 15, 23–32.
Rust, A.C., Cashman, K.V., 2011. Permeability controls on expansion and size distributions of pyroclasts: magma expansion and fragmentation. J. Geophys. Res. 116, n/a-n/a. https://doi.org/10.1029/2011JB008494
Ryshkewitch, E., 1953. Compression strength of porous sintered alumina and zirconia: 9th communication to ceramography. Journal of the American Ceramic Society, 36(2), pp.65-68.
Salvini, S., Coletti, C., Maritan, L., Massironi, M., Balsamo, F., Mazzoli, C., 2023. Exploring the pore system of carbonate rocks through a multi-analytical approach. Environ Earth Sci 82, 564. https://doi.org/10.1007/s12665-023-11234-1
Santoro, L., Putzolu, F., Mondillo, N., Boni, M. and Herrington, R. (2022). Trace element geochemistry of iron-(oxy)-hydroxides in Ni(Co)-laterites: Review, new data and implications for ore forming processes. Ore Geology Reviews, 140, 104501. https://doi.org/10.1016/j.oregeorev.2021.104501.
Shah, M., Sahoo, K.L., Das, S.K., Das, G., 2020. Wear Mechanism of High Chromium White Cast Iron and Its Microstructural Evolutions During the Comminution Process. Tribol Lett 68, 77. https://doi.org/10.1007/s11249-020-01317-6
Siegesmund, S., Dürrast, H., 2011. Physical and Mechanical Properties of Rocks, in: Siegesmund, S., Snethlage, R. (Eds.), Stone in Architecture. Springer Berlin Heidelberg, Berlin, Heidelberg, pp. 97–225. https://doi.org/10.1007/978-3-642-14475-2_3
Somani, A., Nandi, T.K., Pal, S.K., Majumder, A.K., 2017. Pre-treatment of rocks prior to comminution – A critical review of present practices. International Journal of Mining Science and Technology 27, 339–348. https://doi.org/10.1016/j.ijmst.2017.01.013
Sparks, R.S.J., Annen, C., Blundy, J.D., Cashman, K.V., Rust, A.C., Jackson, M.D., 2019. Formation and dynamics of magma reservoirs. Phil. Trans. R. Soc. A. 377, 20180019. https://doi.org/10.1098/rsta.2018.0019
Sun, Y. Pan, A. Ma Y. and Chang, J. 2023. Extraction of alumina and silica from high-silica bauxite by sintering with sodium carbonate followed by two-step leaching with water and sulfuric acid. RSC Adv., 2023, 13, 23254. https://doi.org/10.1039/d3ra03362g.
Tan, S., Li, W., Li, H., Zhou, L. and Yu, M., 2026. Study on Effects of Mineral and Pore Characteristics on Mechanical Behavior and Acoustic Emission of Sandstone. ACS omega, 11(9), pp.14729-14749. https://doi.org/10.1021/acsomega.5c10657.
Tavares, L.M., 2000. Role of particle microstructure in comminution, in: Massacci, P. (Ed.), Developments in Mineral Processing, Oral Session. Elsevier, pp. C4-99. https://doi.org/10.1016/S0167-4528(00)80033-2.
Tijani, M.N. (2023). Geology of Nigeria. In: Faniran, A., Jeje, L.k., Fashae, O.A., Olusola, A.O. (eds) Landscapes and Landforms of Nigeria. World Geomorphological Landscapes. Springer, Cham. https://doi.org/10.1007/978-3-031-17972-3_1.
Timur, A., 1969. Pulsed Nuclear Magnetic Resonance Studies of Porosity, Movable Fluid, and Permeability of Sandstones. Journal of Petroleum Technology 21, 775–786. https://doi.org/10.2118/2045-PA
Ulusay, R. (Ed.), 2015. The ISRM Suggested Methods for Rock Characterization, Testing and Monitoring: 2007-2014. Springer International Publishing, Cham. https://doi.org/10.1007/978-3-319-07713-0
Ulusay, R., Hudson, J.A. (Eds.), 2007. The complete ISRM suggested methods for rock characterization, testing and monitoring: 1974–2006, In: Ulusay, R., Hudson, J.A. (Eds.), Suggested Methods Prepared by the Commission of Testing Methods. ed. (for the ISRM Turkish National Group), Kozam Ofset, Ankara, Turkey.
Ündül, Ö. (2012). Assessment of mineralogical and petrographic factors affecting petrophysical properties, strength and cracking processes of volcanic rocks. Eng. Geol. 2016, 210, 10 – 22.
Upadhyay, R.K., Venkatesh, A.S. and Roy, S. (2010). Mineralogical Characteristics of Iron Ores in Joda and Khondbond Areas in Eastern India with Implications on Beneficiation. Resource Geology Vol. 60, No. 2: 203–211. https://doi.org/10.1111/j.1751-3928.2010.00126.x.
Wang, M., Xie, J., Guo, F., Zhou, Y., Yang, X., Meng, Z., 2020. Determination of NMR T2 Cutoff and CT Scanning for Pore Structure Evaluation in Mixed Siliciclastic–Carbonate Rocks before and after Acidification. Energies 13, 1338. https://doi.org/10.3390/en13061338
Way, D., McKee, D., Pease, J., 2021. Comminution and Mineral Separation—Geological Input to Metallurgy. SEG Discovery 28–41. https://doi.org/10.5382/Geo-and-Mining-12
Williams, R.A., 1993. Processing problematic ores. Minerals Engineering 6, 809–816. https://doi.org/10.1016/0892-6875(93)90055-R
Wills, B.A., Atkinson, K., 1993. Some observations on the fracture and liberation of mineral assemblies. Minerals Engineering 6, 697–706. https://doi.org/10.1016/0892-6875(93)90001-4
Woakes, M., Rahaman, M.A., Ajibade, A.C., 1987. Some metallogenetic features of the Nigerian basement. Journal of African Earth Sciences (1983) 6, 655–664. https://doi.org/10.1016/0899-5362(87)90004-2
Xie, W.-Q., Liu, X.-L., Zhang, X.-P., Liu, Q.-S., Wang, E.-Z., 2025. A review of test methods for uniaxial compressive strength of rocks: Theory, apparatus and data processing. Journal of Rock Mechanics and Geotechnical Engineering 17, 1889–1905. https://doi.org/10.1016/j.jrmge.2024.05.003
Xu, S., Zhao, Y., Wang, M. and Shi, X. (2018). Quantification of Different Forms of Iron from Intact Soil Cores of Paddy Fields with Vis-NIR Spectroscopy. Soil Sci. Soc. Am. J., 82(6), 1497-1511. https://doi.org/10.2136/sssaj2018.01.0014.
Xu, Z., Lin, M., Jiang, W., Cao, G., Yi, Z., 2020. Identifying the comprehensive pore structure characteristics of a rock from 3D images. Journal of Petroleum Science and Engineering 187, 106764. https://doi.org/10.1016/j.petrol.2019.106764.
Yang, Z., Song, Z., Ding, X., Michele Victoire, M.N., Abdoul Wahab, A.M., Oumar, B., Yang, F., Yusuf Ibrahim, A., Gao, Z., Long, Z., 2025. Investigating slope stability of multiple stopes prone to instability in the Ziluoyi iron ore mining site. Sci Rep 15, 1900. https://doi.org/10.1038/s41598-025-85770-0
Yao, Y., Liu, D., 2012. Comparison of low-field NMR and mercury intrusion porosimetry in characterizing pore size distributions of coals. Fuel 95, 152–158. https://doi.org/10.1016/j.fuel.2011.12.039
Yao, Y., Liu, D., Cai, Y., Li, J., 2010a. Advanced characterization of pores and fractures in coals by nuclear magnetic resonance and X-ray computed tomography. Sci. China Earth Sci. 53, 854–862. https://doi.org/10.1007/s11430-010-0057-4
Yao, Y., Liu, D., Che, Y., Tang, D., Tang, S., Huang, W., 2010b. Petrophysical characterization of coals by low-field nuclear magnetic resonance (NMR). Fuel 89, 1371–1380. https://doi.org/10.1016/j.fuel.2009.11.005
Yao, Y., Liu, D., Liu, J., Xie, S., 2015. Assessing the Water Migration and Permeability of Large Intact Bituminous and Anthracite Coals Using NMR Relaxation Spectrometry. Transp Porous Med 107, 527–542. https://doi.org/10.1007/s11242-014-0452-y
Yao, Y., Liu, J., 2019. Petrophysical Characterization of the Pore Structure of Coal, in: Petrophysical Characterization and Fluids Transport in Unconventional Reservoirs. Elsevier, pp. 21–36. https://doi.org/10.1016/B978-0-12-816698-7.00002-4
Yao, Y., Sun, X., Zheng, S., Wu, H., Zhang, C., Liu, Y., Chang, Y., 2021. Methods for Petrological and Petrophysical Characterization of Gas Shales. Energy Fuels 35, 11061–11088. https://doi.org/10.1021/acs.energyfuels.1c01475
Zhai, H. Canbulat, I., Zhang, C., Watson, J. and Gao, M. 2025. Combined effects of discontinuities and intact rock on weak rock at various scales, Journal of Rock Mechanics and Geotechnical Engineering,17(12), 7676-7690. https://doi.org/10.1016/j.jrmge.2025.01.053.
Zhang, J., Tao, G., Huang, L., Yuan, L., 2010. Porosity models for determining the pore-size distribution of rocks and soils and their applications. Chin. Sci. Bull. 55, 3960–3970. https://doi.org/10.1007/s11434-010-4111-6
Zhang, Q.B., Zhao, J., 2014. Quasi-static and dynamic fracture behaviour of rock materials: phenomena and mechanisms. Int J Fract 189, 1–32. https://doi.org/10.1007/s10704-014-9959-z
Zhu, C., Zhu, E., Wang, B., Li, J., Yao, T., Zhang, Z., 2025. Effect of Porosity and Pore Size on the Axial Compressive Properties of Recycled Aggregate Concrete. Materials 18, 2830. https://doi.org/10.3390/ma18122830
Zuo, W., Shi, F., 2016. Ore impact breakage characterisation using mixed particles in wide size range. Minerals Engineering 86, 96–103. https://doi.org/10.1016/j.mineng.2015.12.007
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