Assessing the Influence of Aluminum Dopant on the Morphological and Structural Characteristics of NiS Thin Film Material Deposited by Chemical Bath Deposition Technique

Authors

  • Emmanuel Ifeanyi Ugwu
    Nigerian Army University, Biu
  • Barnaba Abel Adeiza
    Nigerian Army University, Biu
  • Hilary Uche Igwe
    Ebonyi State University Abakaliki
  • Ikpughul Sunday Iyua
    Nigerian Army University, Biu

Keywords:

Assessment, Aluminum, Structural and Morphological properties, Chemical Bath Deposition, Dopant, Nickel sulphide

Abstract

Based on the influence of dopant like aluminum on some sulphide based thin film materials it has become paramount to carry out an assessment of chemical bath deposited Nickel sulphide doped with aluminum has been carried with   the intension to ascertain the impact of the dopant concentration on the morphological and structural properties of the as-deposited NiS thin film sample and the aluminum doped, AlNiS thin film with different concentration of aluminum. It was revealed from the result as obtained from the work that both the morphological and structural properties that there were tremendous effect on the crystallinity, grain-size as depicted in figures and computed values in which the values of the  lattice constant, dislocation density, micro-strain and grain-size as computed at the same preferred plane within the same diffraction angles are found to  vary thereby indicating that there  is clear evidence of the  effect of aluminum doping concentration on the  Nickel sulphide thin film developed with aluminum.

Dimensions

Abdallah B., Ismail A., Kashoua H. and Zetoun, W. (2018). Effects of deposition time on the morphology, structural, and optical properties of PbS thin films prepared by CBD. Journals of nanomaterials.

Adelifard M., Eshghi H. and Mohagheghi M.M.B. (2012). Comparative studies of spray pyrolysis deposited copper sulfide nanostructural thin films on glass and FTO coated glass. Bull. Mater. Sci. 35:739–744.

Adewinbi S. A., Busari R. A., Animasahun L. O., Motoso E. and Taleatu B. A. (2021). “Effective pseadocapacitive performance of binder free transparent α-U2O3 thin film electrode: Electrochemical and some surface probing”, PhydicaB: Condensed Matter 413260. https://doi.org/10.1016/j.physb.2021.413260.

Adeyeba O.A. Ugwu E.I. and Busari R.A. (2022). Influence of Ligand on the Morphological, Electrical, Optical and Solid-State Properties of Chemical Bath Deposited Lead Sulphide Thin Film. Journal of Materials Science Research and Reviews. 10(4):16-31

Ahmed H.S., Mohammed R.Y. and Khalil M.H. (2021,) Effects of Deposition Time and PH on The Characterization of Chemically Synthesized Composite Nano-Wires of Cu2S Thin Films. Sci. J. Univ. Zakho. 9:184–192.

Anuar K, Ho S.M., Lim K.S. and Nagalingam S. (2011). SEM, EDAX and UV-Visible studies on the properties of Cu2S thin films. Chalcogenide Letters. 2011, 8; 405-410.

Aydin E., Sankir M. and Sankir N.D., (2014). Influence of silver incorporation on the structural, optical and electrical properties of spray pyrolyzed indium sulfide thin films. J. Alloy. Compd. 603:119–124.

Benhaoua A., Rahal A. and Benhaoua B. (2014). “Effect of Fluorine doping on the Structural, Optical and Electrical properties of SnO2 thin films prepared spray ultrasonic”. Superlattices and Microstructures, 70: 61-69.

Busari M.A., Raheem I. and Sulaiman, K. (2020). Synthesis and Characterization of Ternary and Quaternary Chalcogenide Thin Films. Thin Solid Films, 42(6), 789-802.

Busari R.A., Taleatu B.A., Adewinbi S.A., Adewumi O.E., Omotoso E., Oyedotun K.O and Fasasi, A.Y. (2020). Synthesis and surface characterization of electrodeposited quaternary chalcogenide Cu2ZnxSnyS1+x+2 y thin film as transparent contact electrode, Bull. Mater. Sci. 43:83.

Chen F., Deng D., and Lei Y., (2014). Preparation and photovoltaic properties of the composite based on porous InS films and PCPDTBT. J. Mater. Sci.: Mater. Electron. 25:2244–2247.

Emmanuel Ugwu (2013). Optical and Solid-State Properties of Manganese Sulphide (MnS) Thin Film, Theoretical Analysis, Int. Jnl. of Multiphysics. 11(2): 2017 Zhang X., Du Z. and Li Q. (2021). "Origins of defect generation at high doping levels in sulfide thin films," Journal of Materials Chemistry C, 9:5383-5392

Gashaw H., F. and Abza T. (2019). Short Review of Factors Affecting Chemical Bath Deposition Method for Metal Chalcogenide Thin Films. Int. J. Thin Film. Sci. Technol. 8(3).

Guo K., Chen X., Han J., and Liu Z. (2014). Synthesis of ZnO/Cu2S core/shell nanorods and their enhanced photoelectric performance. J. Sol-Gel Sci. Technol. 72: 92–99.

Gupta A., and Compaan A.D. (2004). All-sputtered 14% CdS/CdTe thin-film solar cell with ZnO: Al transparent conducting oxide. Appl. Phys. Lett. 85:684–686.

Hedlund J.K., Estrada T.G. and Walker A.V. (2020). Chemical Bath Deposition of Copper Sulfide on Functionalized SAMs: An Unusual Selectivity Mechanism. Langmuir. 36:3119–3126.

Ismail R.A., Al-Samarai A.E. and Ali A.M.M. (2020). Effect of molar concentration of CuCl2 on the characteristics of Cu2S film. Opt. Quantum Electron. 52:1–14.

Kadhim A. A., Abdul-Majeed E. I. and Jassim M. M. (2017). “Structural and Optical Properties of PbS Thin Films Deposited by Pulsed Laser Deposited (PLD) Technique at Different Annealing Temperature. International Journal of Physics, 5(1): 1-8. https://www.10.12691/ijp-5-1-1.

Kadhim A., Al-Haddad A. and Abdullah H. (2017). Structural and Optical Properties of NiS Thin Films Grown on Glass Substrates by Pulsed Laser Deposition. Journal of Materials Science and Engineering, 19(3), 789-802

Kar S., Mondal P. and Reddy R. (2021). “Electron microscopy of deteriorated crystallinity in overdoped metal sulfide thin films,” iScience, 24:103283.

Kassim A., Ho S. M., Tan W.T. and Ngai C.F. (2011). Influence of Triethanolamine on the Chemical Bath Deposited NiS Thin Films. American Journal of Applied Sciences, 8 (4): 359-361,

Kassim A.N., Min H.S., Siang L.K., and Nagalingam S.A. (2011) SEM, EDAX and UV-Visible studies on the properties of Cu2S thin films.Chalcogenide Lett. 8:405–410

Khalil M.H., Mohammed R.Y. and Ibrahem, M.A. (2021). The Influence of CBD Parameters on the Energy Gap of ZnS Narcissus-Like Nanostructured Thin Films. Coatings. 11:1131.

Khan R., Suhail A. and Sajjad M. (2018). "Sulphide-Based Thin Films for Photovoltaic Applications." Solar Energy Materials and Solar Cells, 187:72-81.

Kim J, Park S, and Han, L., (2021). “Excess doping and materials stability limits in metal sulfide thin films,” ACS Applied Nano Materials, 4:7552-7560.

Kumar T. and Sankaranarayanan S. (2009). Growth and characterization of CdZnS thin films by short duration microwave assisted chemical bath deposition technique. Chalcogenide Letters 6(10): 555-562.

Leskelä M. and Ritala M. (2003). Atomic Layer Deposition Chemistry: Recent Developments and Future Challenges. Angew. Chem. Int. Ed. 42:5548-5554.

Nefzi C., Souli M., Cuminal Y. and Kamoun-Turki N. (2020). “Effect of substrate temperature on physical properties of Cu2Fe-SnS4 thin films for photo-catalysis applications”. Mater Sci Eng B, Article 114509

Obasi B.I, Osuwa J.C. and Odu D.A. (2016). Effects of varying copper (Cu) ion concentrations of ternary compound of copper iron sulfide (CuFeS) thin films. International Journal of Science and Technology 5(8): 369-373.

Okoli N.L, Udechukwu I.E. and Okpaneje O.T. (2016). Effect of deposition time on optical and solid-state properties of chemically deposited iron copper sulphide (FeCuS) ternary thin films. African Journal of Education, Science and Technology 3(1): 71-8

Ouachtari F., Rmili A., Elidrissi B., Bouaoud A., Erguig H. and Elies P. (2011) Influence of Bath Temperature, Deposition Time and S/Cd Ratio on the Structure, Surface Morphology, Chemical Composition and Optical Properties of CdS Thin Films Elaborated by Chemical Bath Deposition. J. Mod. Phys. 2:1073–1082.

Owoh B. and Ugwu, E.I. (2009). Growth and Optical characterization of Antimony selenide thin film using chemical bath deposition technique. Metallurgy and material engineering, 4(1): 38-41.

Patel R., Shah D. and Desai C. (2016). Influence of Aluminum Doping on the Structural Properties of Nickel Sulphide Thin Films. Thin Solid Films, 72(3): 567-580

Rajathi S., Kirubavathi K. and Selvaraju K. (2014). Structural, Morphological, Optical and Phooluminescence Properties of Nanocrystalline PbS Thin Films Grown by Chemical Bath Deposition. Journal of chemistry.doi: http://dx.doi.org/10.1016/j.arabjc.2014.11.057.

Sagade A. and Sharma R. (2008). Copper sulphide (CuxS) as an ammonia gas sensor working at room temperature. Sensors Actuators B Chem.133:135–143.

Shah D., Patel R. and Q. Chen (2021). “Unexpected defect escalation through doping in nickel sulfide thin films,” Acta Materialia, 211:116928.

Soonmin L., Han S. and Kim J. (2022). Chalcogenide Thin Films for Solar Energy Applications. Solar Energy Materials and Solar Cells, 35(4):567-580.

Tejuca L.G., Fierro J.L.G. and Tascon J.M.D. (1989). Advances in Thin Film Deposition Techniques and Their Applications in Sensors, Solar Cells, and Infrared Detectors. Journal of Thin Film Technology 24(2):123-136.

Zhan Y., Shao Z., Jiang T., Ye J., Wu X., Zhang B., Ding K., Wu D. and Jie J. (2019). Cation exchange synthesis of two-dimensional vertical Cu2S/CdS heterojunctions for photovoltaic device applications. J. Mater. Chem. A. 8:789–796.

EDX image for Pure Sample of Nickel Sulphide

Published

2025-11-14

How to Cite

Ugwu, E. I., Adeiza, B. A., Igwe, H. U., & Iyua, I. S. (2025). Assessing the Influence of Aluminum Dopant on the Morphological and Structural Characteristics of NiS Thin Film Material Deposited by Chemical Bath Deposition Technique. Nigerian Journal of Physics, 34(4), 146-153. https://doi.org/10.62292/10.62292/njp.v34i4.2025.461

How to Cite

Ugwu, E. I., Adeiza, B. A., Igwe, H. U., & Iyua, I. S. (2025). Assessing the Influence of Aluminum Dopant on the Morphological and Structural Characteristics of NiS Thin Film Material Deposited by Chemical Bath Deposition Technique. Nigerian Journal of Physics, 34(4), 146-153. https://doi.org/10.62292/10.62292/njp.v34i4.2025.461

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