UV-VIS SPECTROPHOTOMETER ANALYSIS OF FILM GROWN USING NATURAL DYE FROM LAWSONIA INERMIS (HENNA PLANT)

Main Article Content

I. F. Okoye
I. O. Alaekwe
O. Abba

Abstract

The films were grown on the substrate using natural dye extracted from Henna plant with water extraction method. The dye was prepared using five grams (5g) of Lawsonia Inermis (Henna Plant) and the mixture of water and methanol 60ml (50:50 ratios). The five grams (5g) of leave and 60ml of mixed measured solvent was grinded for five minutes. The dyes solution extracted were centrifuged at a speed of the revolution centrifugation per minute of 3000rpm to separate the solid fragment from the solution using centrifugation filtering machine. The films were sensitized using the dye and the performance of this dye was carefully examined on the fluorine doped tin oxide film. The films were studied for its optical properties using Spectrophotometer system – UV 752 Axion Medical Ltd Uk, Solar simulator, model 4200-scs semiconductor characterization system was used to studied the power voltage characterization of the grown films while the Tauc model was used to obtain the optical energy band gap of 3.50 eV. The transmittance spectrum was shown, while the nature of the Absorbance of Dyed TiO2 was studied. The behavior of the Absorption Coefficient of Dyed TiO2 was also investigated. The Current/Voltage and power/voltagePerformances of TiO2-based DSSCs using Lawsonia inermis (Henna plant) plant natural dye extracts was investigated and the solar simulation result of DSSCs developed in this research are listed as follows; (Isc) = (0.242 mA), (Voc) = 0.375 V, FF(%) = 50.89%, and MPPT |Mw| = 0.046 Mw for Henna dyed TiO2, while the conversion efficiency ɳ(%) of the dye sensitized solar cell was 0.046%.

Downloads

Download data is not yet available.

Article Details

How to Cite
Okoye, I. F., Alaekwe, I. O., & Abba, O. (2021). UV-VIS SPECTROPHOTOMETER ANALYSIS OF FILM GROWN USING NATURAL DYE FROM LAWSONIA INERMIS (HENNA PLANT). Nigerian Journal of Physics, 30(2), 135–139. Retrieved from https://njp.nipngr.org/index.php/njp/article/view/104
Section
Articles

References

Okoye, I. F., Nwokoye, A.O.C. and Ahmad, G. (2021).Power Voltage Characteristics of Fabricated Dssc Incorporating Multiple Organic Dyes as Photo-sensitizer, Energy and power engineering, Vol.13 No. 6: 221-235.

Al-Rawashdeh, N.A.F., Albiss, B.A. and Yousef, M.H.I. (2018). Graphene-Based Transparent Electrodes for Dye Sensitized Solar Cells. IOP Conf. Ser. Mater. Sci. Eng., 012019:305.

Ananthakumar, S., Balaji, D., Ram, K., and Sridharan, M.B. (2019). Role of co-sensitization in dye-sensitized and quantum dot-sensitized solar cells.

Nwokoye, A. O. C. and Okoye, I. F. (2020).Profilo-matry Analysis of Flourine Doped Tin Oxide (FTO) Film and the Semiconductor Properties of Organic Dye FromSenna Plant as a Photosensitizer, Der ChemicaSinica., 11(1): 2.

Andery, L., Noramaliyana, H.M., Kushan, T., Chandrakanthi, R.L., Linda, B.L., Sarath, B. and Piyasiri, E. (2014).Higher Performance of DSSC with Dyes from Cladophora sp. As Mixed Cosensitizer through Synergistic Effect. Hindawi Publishing Corporation, Journal of Biophysics.

Macht, B., Turrión, M,,Barkschat, A., Salvador, P., Ellmer, K. and Tributsch, H. (2002). Patterns of efficiency and degradation in dye sensitization solar cells measured with imaging techniques. Solar Energy Materials and Solar Cells, Volume 73: 163-173.

Brian, E.H., Eric, T.H., Paul, B.A., Jun-Ho, Y., Pascal, C., Toma’s, T., Jean, M. J., Khaja, N., Michael, G. and Michael, D.M. (2009). Increased light harvesting in dye-sensitized solar cells with energy relay dyes.

Okoye, I. F (2020).Basic Applications in Energy and Power. Ahmadu Bello University Publisher and Press Limited, Zaria, Kaduna State, Nigeria.

Calogero, G, and Di-Marco, G. (2008).Red sililian orange and purple eggplant fruits as natural sensitizers for dye-sensitized solar cells, J. Solar Energy Mater, 92, 1341-1346.

Calogero, G., Di-Marco, G., Cazzanti, S., Caramoni, S., Argazzi, R., Carlo, A.D. and Bignozzi, C.T. (2010). Efficient dye-sensitized solar cells using red turnip and purple wild sicilian prickly pear fruits, Int. Journal Mol. Sci., 11, 254-267.

Gerrit, B. (2019). Improving the Performance of Dye-Sensitized Solar Cells. Journal of Physical Chemistry and Chemical Physics.

Hug, H., Bader, M, Mair. P. and Glatzel, T. (2013). Biophotovoltaics: Natural pigments in dye- sensitized solar cells, J of Applied Energy, 115: 216-225.

Ugwu, L.O, Ozuomba, J.O., Ekwo, P.I. and Ekpunobi, A.J. (2015). The Optical properties of anthocyanin –doped nanocrystalline – TiO2 and the photovoltaic efficiency on DSSC, Der Chemica Sinica. 6(11): 42-48.

Kabirad, F., Bhuiyan, M.M., Manira, M.S., Rahaman, M.S., Khan,. M.A. and Ikegamic, T.I. (2019). Development of dye-sensitized solar cell based on combination of natural dyes extracted from Malabarspinach and red spinach. Journal of Nanoscale Rest Lett.25: 198-201.

Ekanayake, A.W., Kumara, G.R.A., Rajapaksa, R.M.G. and Pallegedara, A. (2015). Increasing the Efficiency of a Dye-Sensitized Solid-State Solar Cell by Iodine Elimination Process in Hole Conductor Material.

Ozuomba, J., Ekpunobi, A. and Ekwo, P. (2011). The photovoltaic performance of dye-sensitized solar cell based on Chlorin local dye. Chalcogenide Letters, 8 (3), pp. 155-161.

Murakoshi, K., Kogure, R. and Yanagida, S. (1997). Solid state dye-sensitized TiO2 solar cell with polypyrrole as hole transport layer. J Chem. Letter.5: 471-472.

Okoli, D.N., G.C. Okeke, and A.J. Ekpunobi (2010). Optical Properties of Chemical Bath Deposited Ag2S Thin Films. Pacific Journal of Science and Technology, 11(1): 411-415.

Ezenwa, I.A, and Ekpunobi, A. J. (2010).Deposition and Characterization of Cds Thin Film by Chemical Bath Method. The Pacific journal of science and Technology, USA. 11: 435-439.

Macht, B., Turrión, M., Barkschat, A., Salvador, P., Ellmer, K. and Tributsch, H. (2002). Patterns of efficiency and degradation in dye sensitization solar cells measured with imaging techniques. Solar Energy Materials and Solar Cells. Volume73: 163-173.

Andualem, A. and Demiss, S. (2018). Review on Dye-Sensitized Solar Cells (DSSCs) Edelweiss AppliSci Tech., 2: 145-150.

Brian, E.H., Eric, T.H., Paul, B.A., Jun-Ho, Y., Pascal, C., Toma´s, T., Jean, M. J., Khaja, N., Michael, G. and Michael, D.M. (2009). Increased light harvesting in dye sensitized solar cells with energy relay dyes.

Matt-Law, D. (1996). Calculation of the photocurrent-potential characteristics for regenerative sensitized semi-conductor electrodes, J. Solar Energy Materials and Solar Cells, 44, 119-155.

Lee, Y. and Kang, M. (2010). The optical properties of nanoporous structured titanium dioxide and the photovoltaic efficiency on DSSC, Mat. Chem. Phy., 122: 284-289.