Determination of Photon Energy Absorption in Epoxy-Based Metallic Composite Samples

Authors

Keywords:

Polymer Composite, NaI(Tl) Scintillation Detector, Mass Attenuation Coefficient, Photon Attenuation, XCOM, High-Z fillers

Abstract

This study investigates the absorption of photon energy and the radiation-shielding efficacy of epoxy-based metallic composites that are reinforced with different weight fractions of bismuth oxide (Bi₂O₃) and barium sulfate (BaSO₄). Increasing the loading of Bi₂O₃ from 14.29% to 85.71% resulted in a corresponding increase in composite density, from 2.65 g/cm³ to 5.86 g/cm³. This enhancement in density, along with the higher atomic number of Bi₂O₃ relative to BaSO₄, contributed to improved ionizing-radiation absorption. Key attenuation parameters, such as mass attenuation coefficient (μm), effective atomic number (Zeff), effective electron density (Neff), and half-value layer (HVL), were assessed over photon energies ranging from 81 to 1332.5 keV. Experimental values closely aligned with theoretical XCOM data, validating significant photoelectric absorption at low energies, where the mass attenuation coefficient increased by up to 98% in high-Z-loaded samples. Composites containing increased Bi₂O₃ fractions exhibited enhanced photon attenuation, decreased half-value layer (HVL), and higher effective atomic number (Zeff) compared to BaSO₄-rich samples, indicating the shielding benefits of high-Z fillers. BaSO₄ enhanced structural uniformity and mechanical integrity, particularly complementing Bi₂O₃ in low-energy regimes. Neff diminished as photon energy increased, indicating a lower probability of photon–electron interactions at higher energies.

Dimensions

Abualroos, N. J., Ahmed, M., Alajerami, Y., & Basha, A. (2022). Radiation attenuation effectiveness of polymer-based composites. Radiation Physics and Chemistry, 222, 111070.

Akkurt, İ., Altınsoy, N., Çelik, A., & Mavi, B. (2014). Performance of NaI (Tl) detector for gamma-ray spectroscopy. Journal of Radiation Research and Applied Sciences, 7(4), 393–398.

Agostinelli, S., Allison, J., Amako, K., Apostolakis, J., Arce, P., Asai, M., Wright, D. (2003). GEANT4—A simulation toolkit. Nuclear Instruments and Methods in Physics Research, 506(3), 250–303.

Aldhuhaibat, M. J. R., Mahdi, K., & Hassan, A. (2021). Improved gamma radiation shielding traits of epoxy composites: Experimental and XCOM comparison. Radiation Physics and Chemistry 179, 109183.

Berger, M. J., & Hubbell, J. H. (1987). XCOM: Photon cross sections database. National Institute of Standards and Technology.

Hedaya, A., Mahmoud, K., & El-Sayed, A. (2022). Effect of Bi₂O₃ particle size on the radiation-shielding capacity of epoxy composites. Polymer, 16(15), 2125. .

Hubbell, J. H., & Seltzer, S. M. (1995). Tables of X-ray mass attenuation coefficients and mass energy-absorption coefficients. NIST.

Karabul, Y., Hassan, H., & Turkmen, I. (2020). Assessment of epoxy-based micro- and nano-Bi₂O₃ and WO₃ composites for radiation shielding. Radiation Physics and Chemistry, 26, 104423.

Khalil, M. M., Hassan, A., & El-Aziz, A. (2024). Impact of nano-Fe₂O₃ on radiation parameters of epoxy composites. Scientific Reports, 14, Article 21940.

Mahmoud, K. (2020). Gamma attenuation coefficients of metal-oxide reinforced polymer systems. Journal of Radiation Research and Applied Sciences, 13(1), 1–10.

Mahmoud, K. G., El-Sayed, A., & Ramadan, T. (2020). Monte Carlo investigation of gamma radiation shielding for Bi₂O₃–epoxy composites. Applied Sciences, 13(3), 1757.

Marashdeh, M., Ababneh, A., & Al-Ajlouni, A. (2016). Determination of the attenuation coefficients of epoxy composites. Journal of Applied Polymer Science, 133(12).

Reeder, P. L., Cooper, J., & Ely, J. H. (2004). Performance of large NaI (Tl) gamma-ray detectors (PNNL-14679). Pacific Northwest National Laboratory.

Safari, A., Jafari, M., & Rezaei, M. (2020). Development of lead-free materials for radiation shielding: A review. Journal of Biomedical Physics and Engineering, 14(3), 229–244.

Elmahroug, Y., & Elbashir, B. (2015). Mass attenuation coefficients and shielding effectiveness of epoxy composites. Applied Radiation and Isotopes, 100, 21–28.

Kumar, A., Singh, P., & Kaur, P. (2021). Structural and shielding characterization of Bi₂O₃–epoxy composites. Journal of Nuclear Materials, 552, 152–160.

Limkitjaroenporn, P., Kaewkhao, J., & Chewpraditkul, W. (2013). Gamma-ray attenuation properties of metal-doped polymer composites. Radiation Physics and Chemistry, 85, 109–115.

Mostafa, A. M. (2014). Optical and gamma-shielding properties of Fe₂O₃ and Bi₂O₃-filled composites. Journal of Alloys and Compounds, 617, 625–632.

Prasad, S. G., & Reddy, K. R. (2018). Determination of mass attenuation coefficients in polymeric materials containing high-Z additives. Radiation Effects and Defects in Solids, 173(9–10), 760–772.

Rammah, Y. S., Elmahroug, Y., & Sayyed, M. I. (2019). Photon attenuation parameters of various lead-free composites. Journal of Non-Crystalline Solids, 509, 80–89.

Sharma, M. K., & Singh, R. (2020). Shielding behavior of bismuth-reinforced polymer composites at photon energies up to 1.33 MeV. Materials Today Communications, 25, 101–112.

Singh, V. P., & Badiger, N. M. (2015). Effective atomic numbers for composite materials exposed to gamma radiation. Nuclear Engineering and Design, 292, 175–182.

Tochaikul, G., Supakun, P., & Khumkong, P. (2025). Enhancing radiation shielding capabilities using epoxy-resin composites reinforced with coral-derived calcium carbonate. Polymers, 17(1), 113.

Tonguc, B., Ozdemir, Y., & Yılmaz, E. (2021). Gamma-ray energy absorption in nano- and micro-scale Bi₂O₃ polymer composites. Radiation Physics and Chemistry, 188, 109–117.

Wang, B., Li, Z., Chen, J., & Zhao, Y. (2023). A comparative study between pure bismuth/tungsten and the bismuth tungsten oxide for flexible shielding of gamma/X rays. Radiation Physics and Chemistry, 208, 110906.

Published

2026-02-18

How to Cite

Makinde, O. S., Aremu, O. A., Adejuwon, O. S., & Oni, O. M. (2026). Determination of Photon Energy Absorption in Epoxy-Based Metallic Composite Samples. Nigerian Journal of Physics, 35(2), 1-8. https://doi.org/10.62292/njp.v35i2.2026.490

How to Cite

Makinde, O. S., Aremu, O. A., Adejuwon, O. S., & Oni, O. M. (2026). Determination of Photon Energy Absorption in Epoxy-Based Metallic Composite Samples. Nigerian Journal of Physics, 35(2), 1-8. https://doi.org/10.62292/njp.v35i2.2026.490

Most read articles by the same author(s)